Bromido(dodecafluorosubphthalo­cyaninato)boron(III)

نویسندگان

  • Graham E. Morse
  • Jozef F. Maka
  • Alan J. Lough
  • Timothy P. Bender
چکیده

The title compound, C(24)BBrF(12)N(6) or Br-F(12)BsubPc (BsubPc is boronsubphtalocyanine), has a bowl-shaped structure with an approximate mol-ecular C(3v) symmetry characteristic of boronsubphthalocyanine compounds. In the crystal, mol-ecules are arranged in one-dimensional columns and the boron-subphthalocyanine units within each column are offset and angled in a bowl-to-ligand packing arrangement such that the axial Br atom rests in the aromatic concaved bowl of the neighboring subphthalocyanine with an inter-molecular Br⋯B distance of 3.721 (3) Å.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010